Product ID:EPMM0015,1,1,2-TRICHLOROTRIFLUOROETHANE SOLUTION IN METHANOL
MSDS Date:03/21/1994
FSC:6550
NIIN:00N062213
MSDS Number: BYGNQ

EM SCIENCE

400 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

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Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE

70 GIBBSTOWN, NJ 08927 US

Telephone: 800-424-9300 (CHEMTREC)

Cage: DO242

ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 0.02%

OSHA PEL 1000 PPM

ACGIH TLV: 1000PPM/1250STEL

METHANOL (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.98%

OSHA PEL 200 PPM, S

ACGIH TLV: 200PPM/250STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY

RTECS: 9999999ZZ

CNDTNS (SEE YOUR SFTY EQUIP SUPP). ENGINEERING

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: TOX BY INGEST & INHAL. CAN BE
TOX BY SKIN ABSORPTION. AFTER INGEST/INHAL, INITIAL SYMP MAY BE
ONLY THAT OF MILD INTOXICATION, BUT MAY BECOME SEV AFTER 12-18 HRS.
AFFECTS CNS, ESPECIALLY OPTIC N ERVE. CHRONIC: MARKED IMPAIRMENT OF
VISION & ENLARGEMENT OF LIVER HAS BEEN REPORTED W/CHRONIC EXPOS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MAY ALSO CAUSE DMG TO KIDNEYS & CNS.
CAUSES DIZZ, NAUS, MUSCLE WEAK, NARCOS, RESP FAILURE. INGEST CAN
PRODUCE BLINDNESS (AS LITTLE AS 30ML)/DEATH (AS LITTLE AS 100ML).
PRLNG/RPTD SKIN CONT M AY CAUSE IRRIT. FETAL DEVELOPMENT ABNORM &
EFTS ON EMBRYO/FETUS HAVE BEEN REPORTED FROM PRLNG EXPOS TO METHYL
(SUP DAT)
Medical Cond Aggravated by Exposure:SKIN CONDITIONS, EYE PROBLEMS,
IMPAIRED LIVER OR KIDNEY FUNCTION.

First Aid:GET MED ASSIST FOR ALL CASES OF OVEREXP. SKIN: IMMED FLUSH
THORO W/LARGE AMOUNTS OF WATER. EYES: IMMED FLUSH THORO W/WATER FOR
AT LEAST 15 MINUTES. INHAL: REMOVE TO FRESH AIR. GIVE ARTIFICIAL
RESPIRAT ION IF BREATHING HAS STOPPED. INGEST: IF CONSCIOUS, DRINK
WATER & INDUCE VOMITING IMMED AS DIRECTED BY MED PERS. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCON PERS. REMOVE CONTAM CLTHG & WASH
BEFORE REUSE.

Flash Point Method:TCC
Flash Point:52.0F,11.1C
Lower Limits:6.7%
Upper Limits:36.5%
Extinguishing Media:USE WATER SPRAY, FOAM, DRY CHEMICAL, OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE & EXPLO HAZ. CLSD CONTRS
MAY EXPLODE UPON HEATING. VAP CAN TRAVEL DIST TO IGNIT SOURCE &
FLASH BACK. THERMAL DECOMP PRODS MAY INCL HCL (SUP DAT)

Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT LISTED
UNDER CONTROL MEASURES SECTION. ELIMINATE ANY IGNITION SOURCES
UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLOSION OR FIRE HAZARDS.
CONTAIN THE RELEASE AND ELI MINATE ITS SOURCE, IF THIS CAN BE DONE
W/OUT RISK.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN COOL
AREA AWAY FROM IGNITION SOURCES & OXIDIZERS. DO NOT BREATHE VAPOR
OR MIST. DO NOT GET IN EYES, ON SKIN/CLOTHING.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS
EXCEEDED (SEE TLV/PEL), NIOSH/MSHA APPRVD AIR-SUPP RESP IS ADVISED
IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA RESP (NEG PR ESS TYPE) UNDER SPECIFIED (ING 4)
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR WITH ADEQUATE VENTILATION.
Protective Gloves:BUTYL RUBBER, VITON OR EQUIVALENT.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EYEWASH AND SAFETY EQUIPMENT SHOULD BE
READILY AVAILABLE.
Work Hygienic Practices:WASH THORO AFTER HNDLG. DO NOT TAKE INTERNALLY.
Supplemental Safety and Health
TRADE NAME/PART #: SOLUTION IN METHANOL. EXPLO HAZ: & PHOSGENE . EFTS
OF OVEREXP: ALCOHOL IN LAB TESTS INVOLVING PREGNANT RATS.
CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRI
NE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED (ING 3)

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:97 @ 20C
Vapor Density:1.1
Spec Gravity:0.791 (H*2O=1)
Evaporation Rate & Reference:5.9 (BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR LIQUID.
Percent Volatiles by Volume:99.9+

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, REACTIVE METALS.
Stability Condition to Avoid:HEAT, CONTACT WITH IGNITION SOURCES.
Hazardous Decomposition Products:CO*X, FORMALDEHYDE. HCL, PHOSGENE .

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. DISPOSE OF IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.